Electrology is the practice of electrical hair removal to permanently remove human hair. Electrolysis is the actual process of removing hair using electricity.

In electrolysis, a qualified professional called an electrologist slides a hair-thin, solid metal probe into each hair follicle without puncturing the skin (when inserted properly). Electricity is delivered to the follicle through the probe, which causes localized damage to the areas that generate hairs, either through the formation of caustic sodium hydroxide (the galvanic method), overheating (thermolysis), or both (the blend method). (source)